Tris(4-methylanilinium) pentachloridoantimonate(III) chloride monohydrate
نویسنده
چکیده
The title compound, (C(7)H(10)N)(3)[SbCl(5)]Cl·H(2)O, consists of 4-methyl-anilinium cations, Cl(-) and [SbCl(5)](2-) anions and water mol-ecules. The five Cl atoms bound to Sb [Sb-Cl = 2.4043 (9)-2.6262 (11) Å] form a square-pyramidal coordination environment. In addition, two [SbCl(5)](2-) anions related by an inversion center are joined by Sb⋯Cl inter-actions [Sb⋯Cl = 3.7273 (14) Å] into an [Sb(2)Cl(10)](4-) dimer with two bridging Cl atoms. The anions, water mol-ecules and ammonium groups of the cations are linked by N-H⋯Cl, N-H⋯O and O-H⋯Cl hydrogen bonds, forming layers parallel to the ac plane. The benzene rings of the 4-methyl-anilinium cations are packed between these layers.
منابع مشابه
Tris(3-methylanilinium) pentachloridoantimonate(III) chloride
In the title compound, (C(7)H(10)N)(3)[SbCl(5)]Cl, the Sb(III) cation is coordinated by five Cl(-) anions in a distorted square-pyramidal geometry, in which the longest Sb-Cl distance of 3.0319 (14) Å indicates a weak coordination bond. In the crystal, the 3-methyl-anilinium cations link with the complex antimonate anions and Cl(-) anions via N-H⋯Cl hydrogen bonds.
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